Chemistry

Zinc Oxide

Zinc Oxide

Zinc Oxide

Definition

Zinc oxide is a white powder, ZnO, which used as a pigment and in cosmetics, dental cement, matches, printing inks, and glass, and in medicine for treatment of skin conditions. It is a dry nanoparticle acting as filler. Solves typical problems for surface finishing like corrosion and scratch. Increases surface hardness, improves UV light resistance and antiseptic effect.

ZnO is a wide-bandgap semiconductor of the II-VI semiconductor group. The native doping of the semiconductor due to oxygen vacancies or zinc interstitials is n-type. ZnO is a white powder that is insoluble in water, and it is widely used as an additive in numerous materials and products including rubbers, plastics, ceramics, glass, cement, lubricants, paints, ointments, adhesives, sealants, pigments, foods, batteries, ferrites, fire retardants, and first-aid tapes. It occurs naturally as the mineral zincite, but most zinc oxide is produced synthetically. Zinc oxide can be used in ointments, creams, and lotions to protect against sunburn and other damage to the skin caused by ultraviolet light. It is also widely used to treat a variety of other skin conditions, in products such as baby powder and barrier creams to treat diaper rashes, calamine cream, anti-dandruff shampoos, and antiseptic ointments.

 

Applications and Uses of Zinc oxide

A very important use is that Zinc Oxide is widely used as the buffer layer in CIGS (Copper Indium Gallium Selenide) solar cells. Some current experiments are focusing on the effect of the thickness of ZnO on maximum power output for the cells.

Zinc oxide also has antibacterial and deodorizing peroperties. For this reason it is employed in medical applications such as in baby powder and creams to treat conditions such as diaper rash, other skin irritations and even dandruff. Due to its reflective properties it is also used in sunblocks and can often be seen on the nose and lips of lifeguards at the beach.

Zinc oxide is also used in:

  • Cigarette Filters
  • Breakfast Cereals
  • Paint pigments
  • Paint coatings
  • Piezoelectricity (delivering alternating current by stretching and releasing zinc oxide nanowires)
  • Lazer diodes
  • Light emitting diodes (LEDs)
  • Spintronics

Other properties of ZnO favorable for electronic applications include its stability to high-energy radiation and its possibility to be patterned by wet chemical etching. Radiation resistance makes ZnO a suitable candidate for space applications. ZnO is the most promising candidate in the field of random lasers to produce an electronically pumped UV laser source.

Zinc Oxide Nanorod Sensors, Spintronics, and Piezoelectricity are all very promising fields and ones to keep an eye on in the nto too distant future.

Structures of Zinc Oxide

Zinc oxide (ZnO) is a unique material that exhibits semiconducting, piezoelectric, and pyroelectric multiple properties. Using a solid-vapor phase thermal sublimation technique, nanocombs, nanorings, nanohelixes/nanosprings, nanobows, nanobelts, nanowires, and nanocages of ZnO have been synthesized under specific growth conditions. It is crystallizes in two main forms, hexagonal wurtzite and cubic zincblende. The wurtzite structure is most stable at ambient conditions and thus most common. The zincblende form can be stabilized by growing ZnO on substrates with cubic lattice structure. In both cases, the zinc and oxide centers are tetrahedral, the most characteristic geometry for Zn(II). ZnO converts to the rocksalt motif at relatively high pressures about 10 GPa.

The growth of nanoring structures can be understood by considering the polar surfaces of the ZnO nanobelt. The polar nanobelt, which is the building block of the nanoring, grows along [1010], with side surfaces ±(1210) and top/bottom surfaces ±(0001), and has a typical width of ∼15 nm and thickness of ∼10 nm.

Side Effects of Zinc Oxid

All medicines may cause side effects, but many people have no, or minor, side effects. A side effect is an unwanted response to a medication when it is taken in normal doses. Side effects can be mild or severe, temporary or permanent. Seek medical attention right away if any of these SEVERE side effects occur:

Severe allergic reactions (rash; hives; difficulty breathing; tightness in the chest; swelling of the mouth, face, lips, or tongue).

This is not a complete list of all side effects that may occur. If you have questions about side effects, contact your health care provider. Call your doctor for medical advice about side effects.