Chlorous Acid – an Inorganic Compound

Chlorous acid has the formula HClO2 and is an inorganic compound. It’s a type of chlorine oxoacid. It is a chlorite conjugate acid. It’s a mild acid. In this acid, chlorine has an oxidation state of +3. The pure substance is unstable, forming hypochlorous acid (Cl oxidation state +1) and chloric acid (Cl oxidation state +5):

2 HClO2 → HClO + HClO3

Although the acid is difficult to obtain in pure form, the conjugate base derived from it, chlorite, is stable. The well-known sodium chlorite is an example of an anion salt. This and related salts are occasionally used in the manufacture of chlorine dioxide.

Preparation

Chlorous acid is the least stable of all the oxyacids of chlorine. It can be prepared by treating a suspension of barium chlorite with sulfuric acid followed by removal of the precipitated barium sulfate. HClO2 can be prepared through the reaction of barium or lead chlorite and dilute sulfuric acid:

Ba(ClO2)2 + H2SO4 → BaSO4 + 2 HClO2

Pb(ClO2)2 + H2SO4 → PbSO4 + 2 HClO2

HClO2 exists only in an aqueous solution. It decomposes rapidly in base to give chlorite and chlorate ions and in acid to give chlorine dioxide and chlorate and chloride ions. There is some indirect evidence for the existence of bromous and iodous acids, but they are even less stable than HCIO2.

Stability

Chlorous acid is a powerful oxidizing agent, but its disproportionation tendency negates its oxidizing potential.

It is a colorless liquid with no discernible aroma when isolated. It is an unstable compound as a result of the dismutation reaction that produces chloric and hypochlorous acid, which is similar to the reaction that produces bromine and iodine analogs. It is an extremely strong oxidizing agent that is incompatible with alkalis and reducing agents. It is widely used as a mouthwash to reduce plaque.

Chlorine is the only halogen that can form the isolable acid HXO2. Bromous acid and iodous acid have never been isolated. There are a few bromites, or salts of bromous acid, but no iodites.

Precaution

This compound is extremely dangerous when it comes into contact with the skin and eyes, or when it is ingested or inhaled. If you have contact lenses and this acid gets into your eyes, remove them and flush your eyes for 15 minutes with running water while keeping your eyelids open. Use no eye ointment. If the chemical comes into contact with your clothing, remove it immediately and take a shower.

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